Rhodium(I) complexes with N-heterocyclic carbenes bearing a 2,3,4,5-tetraphenylphenyl and its higher dendritic frameworks

Hiromichi Sato, Tetsuaki Fujihara, Yasushi Obora, Makoto Tokunaga, Junya Kiyosu, Yasushi Tsuji

Research output: Contribution to journalArticle

36 Citations (Scopus)

Abstract

Novel rhodium(i) complexes with N-heterocyclic carbenes bearing a 2,3,4,5-tetraphenylphenyl and its higher dendritic frameworks were synthesized and the complexes were used as catalysts in rhodium-catalyzed hydrosilylation of α,β-unsaturated ketones to show high 1,4-adduct selectivity.

Original languageEnglish
Pages (from-to)269-271
Number of pages3
JournalChemical Communications
Issue number3
DOIs
Publication statusPublished - Jan 1 2007

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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