Room-temperature synthesis of a covalent organic framework with enhanced surface area and thermal stability and application to nitrogen-doped graphite synthesis

Tomohiro Shiraki, Gayoung Kim, Naotoshi Nakashima

    Research output: Contribution to journalArticlepeer-review

    10 Citations (Scopus)

    Abstract

    We report room-temperature synthesis of a covalent organic framework (COF) using the combination of benzene-1,3,5-tricarbaldehyde and 1,4-phenylenediamine. The method is quite simple and the obtained COF was revealed to have a high surface area and high thermal stability due to its high crystallinity compared to that of the COF synthesized by a conventional solvothermal synthetic method using the same monomer combination. We also synthesized a nitrogen-doped graphite based on carbonization of the COF.

    Original languageEnglish
    Pages (from-to)1488-1490
    Number of pages3
    JournalChemistry Letters
    Volume44
    Issue number11
    DOIs
    Publication statusPublished - 2015

    All Science Journal Classification (ASJC) codes

    • Chemistry(all)

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