Rotaxane type complexation behavior of cyclodextrins with a series of donor-acceptor covarently linked compounds

Tatsuya Morozumi, Takashi Kimura, Tomomi Ujiie, Hiroaki Yonemura, Taku Matsuo, Hiroshi Nakamura

Research output: Contribution to journalArticlepeer-review

Abstract

The complexation behavior of a series of electron donor-accepter (D-A) covalently linked compounds with cyclodextrins (CyDs) has been reviewed. The structure of these complexes showed rotaxane type conformations, which were investigated by means of 1H NMR spectrometry. The complex formations induced a fixation of a conformation of guest D-A molecules, and D-A distances were enlarged. Thus, accurate photo-induced charge transfer behaviors can be discussed.

Original languageEnglish
Pages (from-to)105-110
Number of pages6
JournalJournal of Inclusion Phenomena
Volume50
Issue number1-2
Publication statusPublished - Oct 1 2004

All Science Journal Classification (ASJC) codes

  • Food Science
  • Chemistry(all)
  • Condensed Matter Physics

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