Ruthenium-catalyzed selective and efficient oxygenation of hydrocarbons with water as an oxygen source

Yuichirou Hirai, Takahiko Kojima, Yasuhisa Mizutani, Yoshihito Shiota, Kazunari Yoshizawa, Shunichi Fukuzumi

Research output: Contribution to journalArticle

98 Citations (Scopus)

Abstract

(Chemical Equation Presented) Water is not only the solvent but also the sole oxygen source in the smooth and efficient oxidation of organic compounds catalyzed by a RuII-pyridylamine-aqua complex with CeIV as the oxidant. An intermediate-spin RuIV-oxo complex is formed as the reactive species (see scheme; Sub = substrate). This catalytic system is durable and able to gain high turnover numbers for various substrates.

Original languageEnglish
Pages (from-to)5772-5776
Number of pages5
JournalAngewandte Chemie - International Edition
Volume47
Issue number31
DOIs
Publication statusPublished - Jul 21 2008

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Oxygenation
Ruthenium
Hydrocarbons
Oxygen
Water
Substrates
Oxidants
Organic compounds
Oxidation

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Ruthenium-catalyzed selective and efficient oxygenation of hydrocarbons with water as an oxygen source. / Hirai, Yuichirou; Kojima, Takahiko; Mizutani, Yasuhisa; Shiota, Yoshihito; Yoshizawa, Kazunari; Fukuzumi, Shunichi.

In: Angewandte Chemie - International Edition, Vol. 47, No. 31, 21.07.2008, p. 5772-5776.

Research output: Contribution to journalArticle

Hirai, Yuichirou ; Kojima, Takahiko ; Mizutani, Yasuhisa ; Shiota, Yoshihito ; Yoshizawa, Kazunari ; Fukuzumi, Shunichi. / Ruthenium-catalyzed selective and efficient oxygenation of hydrocarbons with water as an oxygen source. In: Angewandte Chemie - International Edition. 2008 ; Vol. 47, No. 31. pp. 5772-5776.
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