Ruthenium(iv) N-confused porphyrin μ-oxo-bridged dimers: acid-responsive molecular rotors

Osamu Iwanaga, Kazuki Fukuyama, Shigeki Mori, Jun Tae Song, Tatsumi Ishihara, Takaaki Miyazaki, Masatoshi Ishida, Hiroyuki Furuta

Research output: Contribution to journalArticlepeer-review

Abstract

Ruthenium(iv) N-confused porphyrin μ-oxo-bridged complexes were synthesizedviaoxidative dimerization of a ruthenium(ii) N-confused porphyrin complex using 2,2,6,6-tetramethylpiperidine 1-oxyl. The deformed core planes in the dimers conferred a relatively high ring rotational barrier ofca.16 kcal mol−1. Rotation of the complexes was controlled by protonating the peripheral nitrogen.

Original languageEnglish
Pages (from-to)24575-24579
Number of pages5
JournalRSC Advances
Volume11
Issue number40
DOIs
Publication statusPublished - Jul 5 2021

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

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