Seasonal variation in basal emission rates and composition of mono- and sesquiterpenes emitted from dominant conifers in Japan

Sou N. Matsunaga, Shigeru Niwa, Tomoki Mochizuki, Akira Tani, Dai Kusumoto, Yasuhiro Utsumi, Tsutomu Enoki, Tsutom Hiura

Research output: Contribution to journalArticle

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Abstract

Biogenic volatile organic compounds (BVOCs) are known to play an important role in atmospheric chemistry due to their high reactivity and high emission rates. Therefore, in recent decades, many efforts have been made to estimate the emission rates, composition and allocation of the BVOCs. Monoterpenes (MNTs) and sesquiterpenes (SQTs) are major groups of BVOCs and mainly emitted from coniferous trees. There is quite a few reports discussing the seasonality of basal emission rate, which is a normalized emission rate at a set of standard conditions (e.g. temperature, light intensity), of the BVOCs. Three field measurements were conducted using branch enclosure techniques to determine MNTs and SQTs emission measured from mature trees of Cryptomeria japonica and Chamaecyparis obtusa, which are the most dominant trees in Japan and account for about 40-50% of Japanese forest in leaf amount throughout the four seasons in southern Japan in 2010. The results are compared with the measurements for the same compound classes obtained at a suburban area of Tokyo, Japan in 2009. The seasonal variation in the basal emissions of MNTs from both tree species at Shiiba did not show significant seasonal changes. For both tree species, the variations in the basal emission of MNTs differ in the two sites, while those of SQTs showed relatively similar variations. Chemical composition of SQTs showed clear and continued seasonal variations, while MNTs did not show any clear seasonal variation for these tree species at both sites. It can be hypothesized that the emissions of BVOC classes (e.g. MNTs and SQTs) depend on leaf age. In this paper, we discuss about the seasonal variations in the basal emission rates and chemical compositions of BVOCs obtained from the two dominant coniferous tree species in Japan based on nine field measurement campaigns conducted at two different sites.

Original languageEnglish
Pages (from-to)124-130
Number of pages7
JournalAtmospheric Environment
Volume69
DOIs
Publication statusPublished - Apr 1 2013

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monoterpene
coniferous tree
seasonal variation
volatile organic compound
chemical composition
rate
suburban area
atmospheric chemistry
light intensity
seasonality

All Science Journal Classification (ASJC) codes

  • Environmental Science(all)
  • Atmospheric Science

Cite this

Seasonal variation in basal emission rates and composition of mono- and sesquiterpenes emitted from dominant conifers in Japan. / Matsunaga, Sou N.; Niwa, Shigeru; Mochizuki, Tomoki; Tani, Akira; Kusumoto, Dai; Utsumi, Yasuhiro; Enoki, Tsutomu; Hiura, Tsutom.

In: Atmospheric Environment, Vol. 69, 01.04.2013, p. 124-130.

Research output: Contribution to journalArticle

Matsunaga, Sou N. ; Niwa, Shigeru ; Mochizuki, Tomoki ; Tani, Akira ; Kusumoto, Dai ; Utsumi, Yasuhiro ; Enoki, Tsutomu ; Hiura, Tsutom. / Seasonal variation in basal emission rates and composition of mono- and sesquiterpenes emitted from dominant conifers in Japan. In: Atmospheric Environment. 2013 ; Vol. 69. pp. 124-130.
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