Selection of Stripping Reagents from an Organic Solution of Molybdenum-Alkylphosphonic Acid Monoester Complex

Masahiro Goto, Takahiko Kakoi, Makoto Narisako, Kazuo Kondo, Fumiyuki Nakashio

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Stripping reagents of molybdenum(IV) from an organic solution of molybdenum-alkylphosphonic acid monoester complex were examined. It was clarified that aqueous solutions of polyhydroxyalcohol and saccharide are effective as stripping reagents in the above system. Among them, quantitative stripping could be attained by using a mannitol aqueous solution in the pH range above 4. The dependence on the concentration of mannitol and extractant was investigated. It was found that nonionic species of molybdenum forms aqueous-soluble complex with mannitol. From the experimental results, the stripping reaction of molybdenum with mannitol (L) was deduced as follows ∗ [formula omitted].

Original languageEnglish
Pages (from-to)767-769
Number of pages3
Journalkagaku kogaku ronbunshu
Volume18
Issue number5
DOIs
Publication statusPublished - Jan 1 1992

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Molybdenum
Mannitol
Acids

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

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Selection of Stripping Reagents from an Organic Solution of Molybdenum-Alkylphosphonic Acid Monoester Complex. / Goto, Masahiro; Kakoi, Takahiko; Narisako, Makoto; Kondo, Kazuo; Nakashio, Fumiyuki.

In: kagaku kogaku ronbunshu, Vol. 18, No. 5, 01.01.1992, p. 767-769.

Research output: Contribution to journalArticle

Goto, Masahiro ; Kakoi, Takahiko ; Narisako, Makoto ; Kondo, Kazuo ; Nakashio, Fumiyuki. / Selection of Stripping Reagents from an Organic Solution of Molybdenum-Alkylphosphonic Acid Monoester Complex. In: kagaku kogaku ronbunshu. 1992 ; Vol. 18, No. 5. pp. 767-769.
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