Selection of Stripping Reagents from an Organic Solution of Molybdenum-Alkylphosphonic Acid Monoester Complex

Masahiro Goto, Takahiko Kakoi, Makoto Narisako, Kazuo Kondo, Fumiyuki Nakashio

    Research output: Contribution to journalArticlepeer-review

    2 Citations (Scopus)

    Abstract

    Stripping reagents of molybdenum(IV) from an organic solution of molybdenum-alkylphosphonic acid monoester complex were examined. It was clarified that aqueous solutions of polyhydroxyalcohol and saccharide are effective as stripping reagents in the above system. Among them, quantitative stripping could be attained by using a mannitol aqueous solution in the pH range above 4. The dependence on the concentration of mannitol and extractant was investigated. It was found that nonionic species of molybdenum forms aqueous-soluble complex with mannitol. From the experimental results, the stripping reaction of molybdenum with mannitol (L) was deduced as follows ∗ [formula omitted].

    Original languageEnglish
    Pages (from-to)767-769
    Number of pages3
    Journalkagaku kogaku ronbunshu
    Volume18
    Issue number5
    DOIs
    Publication statusPublished - 1992

    All Science Journal Classification (ASJC) codes

    • Chemistry(all)
    • Chemical Engineering(all)

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