TY - JOUR
T1 - Selective catalytic 2e--oxidation of organic substrates by an FeIIcomplex having an N-heterocyclic carbene ligand in water
AU - Fujisaki, Hiroto
AU - Ishizuka, Tomoya
AU - Shimoyama, Yoshihiro
AU - Kotani, Hiroaki
AU - Shiota, Yoshihito
AU - Yoshizawa, Kazunari
AU - Kojima, Takahiko
N1 - Funding Information:
This work has been supported by JST CREST (Grant JPMJCR16P1) and Grants-in-Aid (15H00915, 17H03027, and 18K19089) from the Japan Society of Promotion of Science (JSPS).
PY - 2020/9/4
Y1 - 2020/9/4
N2 - An FeII complex, 1, having a pentadentate ligand with an NHC moiety catalyzes substrate oxidation to afford 2e-oxidized products with high selectivity by suppression of overoxidation in water. A Bell-Evance-Polanyi plot for the substrate oxidation catalyzed by 1 exhibited an inflection point around 86 kcal mol-1, indicating strong C-H abstraction ability of the reactive species derived from 1.
AB - An FeII complex, 1, having a pentadentate ligand with an NHC moiety catalyzes substrate oxidation to afford 2e-oxidized products with high selectivity by suppression of overoxidation in water. A Bell-Evance-Polanyi plot for the substrate oxidation catalyzed by 1 exhibited an inflection point around 86 kcal mol-1, indicating strong C-H abstraction ability of the reactive species derived from 1.
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U2 - 10.1039/d0cc03289a
DO - 10.1039/d0cc03289a
M3 - Article
C2 - 32716434
AN - SCOPUS:85090070524
SN - 1359-7345
VL - 56
SP - 9783
EP - 9786
JO - Chemical Communications
JF - Chemical Communications
IS - 68
ER -