Selective cine substitution of 1-arylethenyl acetates with arylboron reagents and a diene/rhodium catalyst

Jung Yi Yu, Ryosuke Shimizu, Ryoichi Kuwano

Research output: Contribution to journalArticle

28 Citations (Scopus)

Abstract

When the crowd says Bo: A carbon-carbon bond is selectively formed at the β position of 1- arylethenyl acetate when the alkenyl substrate is reacted with arylboronic acids in the presence of a cycloocta-1,5-diene/rhodium catalyst. The choice of the ligand is crucial for the unusual cine substitution.

Original languageEnglish
Pages (from-to)6396-6399
Number of pages4
JournalAngewandte Chemie - International Edition
Volume49
Issue number36
DOIs
Publication statusPublished - Aug 23 2010

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Catalysis

Fingerprint Dive into the research topics of 'Selective cine substitution of 1-arylethenyl acetates with arylboron reagents and a diene/rhodium catalyst'. Together they form a unique fingerprint.

  • Cite this