Selective growth of calcium molybdate whiskers by rapid cooling of a sodium chloride flux

Katsuya Teshima, Kunio Yubuta, Shiori Sugiura, Yoko Fujita, Takaomi Suzuki, Morinobu Endo, Toetsu Shishido, Shuji Oishi

Research output: Contribution to journalArticlepeer-review

28 Citations (Scopus)

Abstract

Long whiskers of calcium molybdate (CaMoO4) were selectively grown by rapid cooling of a NaCl flux. The crystal growth of CaMoO4 was conducted by heating a mixture of solute and flux at 900 °C for 10 h and then cooling to 500 °C at a rate of 270 °C·h-1 or quenching in a furnace with the electric power turned off. The obtained whiskers were colorless and transparent. Transmission electron microscopy images showed that the grown whiskers were of a very good crystallinity. The major constituents were homogeneously distributed throughout the whiskers. Sodium and chlorine atoms from the flux were not detected. Whiskers grown from the solutions were up to 5.2 mm long and 7 μm in diameter. The whiskers were cylindrical in shape with average aspect ratios ranging from 150 to 750, and they elongated dominantly in the 〈110〉 directions.

Original languageEnglish
Pages (from-to)1598-1601
Number of pages4
JournalCrystal Growth and Design
Volume6
Issue number7
DOIs
Publication statusPublished - Jul 2006
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Fingerprint

Dive into the research topics of 'Selective growth of calcium molybdate whiskers by rapid cooling of a sodium chloride flux'. Together they form a unique fingerprint.

Cite this