Selective iodide chemosensing through a redox-active Cu-corrole

Biju Basumatary, Masood Ayoub Kaloo, Vineet Kumar Singh, Ruchika Mishra, Muthuchamy Murugavel, Jeyaraman Sankar

Research output: Contribution to journalArticlepeer-review

12 Citations (Scopus)

Abstract

An electron deficient Cu(iii)-corrole (B) has been identified as a highly selective colorimetric sensor for iodide. A one-electron redox couple between iodide and Cu(iii)-corrole serves as the basis for selectivity. The proposed mechanism has been supported by UV-vis and 19F NMR studies and further by unambiguous identification of Cu(ii) species through EPR.

Original languageEnglish
Pages (from-to)28417-28420
Number of pages4
JournalRSC Advances
Volume4
Issue number54
DOIs
Publication statusPublished - 2014
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

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