Selective ionization of 2,4-xylenol in mass spectrometry using a tunable laser and supersonic jet technique

Hiroko Tsukatani, Hiroki Okudaira, Tomohiro Uchimura, Tomoko Imasaka, Totaro Imasaka

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

A supersonic jet/resonance-enhanced multiphoton ionization/time-of-flight mass spectrum (SSJ/REMPI/TOF-MS) was measured for xylenols and ethylphenols. Sharp and intense peaks were observed in the REMPI spectrum of 2,4-xylenol, and the wavelength of the peak tentatively assigned to the 0-0 transition was the longest among xylenols and ethylphenols. These results suggest that 2,4-xylenol, designated as a Class II chemical substance in the Pollutant Release and Transfer Register (PRTR), can be measured sensitively and selectively even when numerous isomers are present in the sample. 2009

Original languageEnglish
Pages (from-to)599-604
Number of pages6
JournalAnalytical Sciences
Volume25
Issue number5
DOIs
Publication statusPublished - May 1 2009

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Laser tuning
Ionization
Mass spectrometry
Isomers
Wavelength
2,4-dimethylphenol
3,5-xylenol

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry

Cite this

Selective ionization of 2,4-xylenol in mass spectrometry using a tunable laser and supersonic jet technique. / Tsukatani, Hiroko; Okudaira, Hiroki; Uchimura, Tomohiro; Imasaka, Tomoko; Imasaka, Totaro.

In: Analytical Sciences, Vol. 25, No. 5, 01.05.2009, p. 599-604.

Research output: Contribution to journalArticle

Tsukatani, Hiroko ; Okudaira, Hiroki ; Uchimura, Tomohiro ; Imasaka, Tomoko ; Imasaka, Totaro. / Selective ionization of 2,4-xylenol in mass spectrometry using a tunable laser and supersonic jet technique. In: Analytical Sciences. 2009 ; Vol. 25, No. 5. pp. 599-604.
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