Selective strain-promoted azide-alkyne cycloadditions through transient protection of bicyclo[6.1.0]nonynes with silver or gold

Keisuke Adachi; Tomohiro Meguro; Yuki Sakata; Kazunobu Igawa; Katsuhiko Tomooka; Takamitsu Hosoya; Suguru Yoshida

doi:10.1039/d0cc04606j

Selective strain-promoted azide-alkyne cycloadditions through transient protection of bicyclo[6.1.0]nonynes with silver or gold

Keisuke Adachi, Tomohiro Meguro, Yuki Sakata, Kazunobu Igawa, Katsuhiko Tomooka, Takamitsu Hosoya, Suguru Yoshida

Department of Applied Molecular Chemistry

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

Complexation of bicyclo[6.1.0]nonynes with a cationic silver or gold salt results in protection from a click reaction with azides. The cycloalkyne protection using the silver or gold salt enables selective strain-promoted azide-alkyne cycloadditions of diynes keeping the bicyclo[6.1.0]nonyne moiety unreacted. This journal is

Original language	English
Pages (from-to)	9823-9826
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	68
DOIs	https://doi.org/10.1039/d0cc04606j
Publication status	Published - Sept 4 2020

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/d0cc04606j

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abstract = "Complexation of bicyclo[6.1.0]nonynes with a cationic silver or gold salt results in protection from a click reaction with azides. The cycloalkyne protection using the silver or gold salt enables selective strain-promoted azide-alkyne cycloadditions of diynes keeping the bicyclo[6.1.0]nonyne moiety unreacted. This journal is ",

author = "Keisuke Adachi and Tomohiro Meguro and Yuki Sakata and Kazunobu Igawa and Katsuhiko Tomooka and Takamitsu Hosoya and Suguru Yoshida",

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AU - Adachi, Keisuke

AU - Meguro, Tomohiro

AU - Sakata, Yuki

AU - Igawa, Kazunobu

AU - Tomooka, Katsuhiko

AU - Hosoya, Takamitsu

AU - Yoshida, Suguru

PY - 2020/9/4

Y1 - 2020/9/4

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AB - Complexation of bicyclo[6.1.0]nonynes with a cationic silver or gold salt results in protection from a click reaction with azides. The cycloalkyne protection using the silver or gold salt enables selective strain-promoted azide-alkyne cycloadditions of diynes keeping the bicyclo[6.1.0]nonyne moiety unreacted. This journal is

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Selective strain-promoted azide-alkyne cycloadditions through transient protection of bicyclo[6.1.0]nonynes with silver or gold

Abstract

All Science Journal Classification (ASJC) codes

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