Self-assembling properties of 11-ferrocenyl-1-undecanethiol on highly oriented pyrolitic graphite characterized by scanning tunneling microscopy

Lloyd F.N. Ah Qune, Kaoru Tamada, Masahiko Hara

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Abstract

Molecular resolution scanning tunneling microscope (STM) images the spontaneous self-assembly of 11-ferrocenyl-1-undecanethiol ((C5H 5)Fe(C5H4)(CH2)11-SH) forming a large striped-phase on highly oriented pyrolitic graphite (HOPG) at a phenyloctane-HOPG interface. In the image, the alkyl chains lying flat on HOPG appear as bundles in groups of five in the moiré pattern due to lattice mismatch with the underlying HOPG. The ferrocene units appearing as either fuzzy or ring-like structures suggest the random rotation of cyclopentadienyl (Cp) rings sandwiching the central iron ion of the ferrocene moieties with their principal axis either oblique or perpendicular to the HOPG. The ferrocene moieties are more clearly resolved in a mixed film with octanethiol, where the fuzzy or ring-like structures of the ferrocene units are asymmetrically distant from the sulfur head-groups forming alternating rows in the phase segregated image. Both molecules can be clearly distinguished by the length of the molecular rows.

Original languageEnglish
Pages (from-to)119-123
Number of pages5
Journale-Journal of Surface Science and Nanotechnology
Volume6
DOIs
Publication statusPublished - Apr 29 2008

Fingerprint

Scanning Tunnelling Microscopy
Graphite
Scanning tunneling microscopy
assembling
scanning tunneling microscopy
graphite
ring structures
Lattice mismatch
Sulfur
Self assembly
bundles
self assembly
Microscopes
sulfur
Iron
microscopes
Ions
Scanning
iron
Molecules

All Science Journal Classification (ASJC) codes

  • Biotechnology
  • Bioengineering
  • Condensed Matter Physics
  • Mechanics of Materials
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films

Cite this

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abstract = "Molecular resolution scanning tunneling microscope (STM) images the spontaneous self-assembly of 11-ferrocenyl-1-undecanethiol ((C5H 5)Fe(C5H4)(CH2)11-SH) forming a large striped-phase on highly oriented pyrolitic graphite (HOPG) at a phenyloctane-HOPG interface. In the image, the alkyl chains lying flat on HOPG appear as bundles in groups of five in the moir{\'e} pattern due to lattice mismatch with the underlying HOPG. The ferrocene units appearing as either fuzzy or ring-like structures suggest the random rotation of cyclopentadienyl (Cp) rings sandwiching the central iron ion of the ferrocene moieties with their principal axis either oblique or perpendicular to the HOPG. The ferrocene moieties are more clearly resolved in a mixed film with octanethiol, where the fuzzy or ring-like structures of the ferrocene units are asymmetrically distant from the sulfur head-groups forming alternating rows in the phase segregated image. Both molecules can be clearly distinguished by the length of the molecular rows.",
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N2 - Molecular resolution scanning tunneling microscope (STM) images the spontaneous self-assembly of 11-ferrocenyl-1-undecanethiol ((C5H 5)Fe(C5H4)(CH2)11-SH) forming a large striped-phase on highly oriented pyrolitic graphite (HOPG) at a phenyloctane-HOPG interface. In the image, the alkyl chains lying flat on HOPG appear as bundles in groups of five in the moiré pattern due to lattice mismatch with the underlying HOPG. The ferrocene units appearing as either fuzzy or ring-like structures suggest the random rotation of cyclopentadienyl (Cp) rings sandwiching the central iron ion of the ferrocene moieties with their principal axis either oblique or perpendicular to the HOPG. The ferrocene moieties are more clearly resolved in a mixed film with octanethiol, where the fuzzy or ring-like structures of the ferrocene units are asymmetrically distant from the sulfur head-groups forming alternating rows in the phase segregated image. Both molecules can be clearly distinguished by the length of the molecular rows.

AB - Molecular resolution scanning tunneling microscope (STM) images the spontaneous self-assembly of 11-ferrocenyl-1-undecanethiol ((C5H 5)Fe(C5H4)(CH2)11-SH) forming a large striped-phase on highly oriented pyrolitic graphite (HOPG) at a phenyloctane-HOPG interface. In the image, the alkyl chains lying flat on HOPG appear as bundles in groups of five in the moiré pattern due to lattice mismatch with the underlying HOPG. The ferrocene units appearing as either fuzzy or ring-like structures suggest the random rotation of cyclopentadienyl (Cp) rings sandwiching the central iron ion of the ferrocene moieties with their principal axis either oblique or perpendicular to the HOPG. The ferrocene moieties are more clearly resolved in a mixed film with octanethiol, where the fuzzy or ring-like structures of the ferrocene units are asymmetrically distant from the sulfur head-groups forming alternating rows in the phase segregated image. Both molecules can be clearly distinguished by the length of the molecular rows.

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