Self-encapsulation of homogeneous catalyst species into polymer gel leading to a facile and efficient separation system of amine products in the Ru-catalyzed reduction of carboxamides with polymethylhydrosiloxane (PMHS)

Yukihiro Motoyama, Kaoru Mitsui, Toshiki Ishida, Hideo Nagashima

Research output: Contribution to journalArticle

148 Citations (Scopus)

Abstract

A practical procedure for production of amines is offered by the ruthenium-catalyzed reduction of carboxamides with polymethylhydrosiloxane, in which encapsulation of the catalyst species into the formed insoluble siloxane resins contributes to the separation of both metallic and siloxane residues from the product.

Original languageEnglish
Pages (from-to)13150-13151
Number of pages2
JournalJournal of the American Chemical Society
Volume127
Issue number38
DOIs
Publication statusPublished - Sep 28 2005

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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