Self-propagating high-temperature synthesis of La(Sr)Ga(Mg)O3-δ for electrolyte of solid oxide fuel cells

Hiroyuki Ishikawa, Makiko Enoki, Tatsumi Ishihara, Tomohiro Akiyama

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

This paper describes self-propagating high-temperature synthesis (SHS) of an electrolyte for solid oxide fuel (SOFC), in comparison to a conventional solid-state reaction method (SRM). Doped-lanthanum gallate: La0.9Sr0.1Ga0.8Mg0.2O3-δ (LSGM9182) and LSGM9173 as the SOFC electrolyte, was prepared by the SHS and sintered at different temperatures, for measuring the electrical conductivity of the sintered LSGM and the power generating performance at 1073 K, in comparison to the SRM. In the SHS, the LSGM powders with smaller size were obtained and easily sintered at the 100 K-lower temperature, 1673 K, than in the SRM. Most significantly, the electrical conductivity of the sintered LSGM9182 was as high as 0.11 S cm-1 and its maximum power density was a value of 245 mW cm-2 in the cell configuration of Ni/LSGM9182 (0.501 mm in thickness)/Sm0.5Sr0.5CoO3. The conclusion was that the proposed SHS-sintering method with many benefits of minimizing the energy requirement and the processing time in the production, easing temperature restriction for the sintering, and improving the electrolyte performance up to a conventional level is practicable for producing the LSGM-electrolyte of SOFC at an intermediate-temperature application.

Original languageEnglish
Pages (from-to)246-251
Number of pages6
JournalJournal of Alloys and Compounds
Volume430
Issue number1-2
DOIs
Publication statusPublished - Mar 14 2007

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Solid oxide fuel cells (SOFC)
Electrolytes
Sintering
Temperature
Lanthanum
Solid state reactions
Powders
Oxides
Processing
Electric Conductivity

All Science Journal Classification (ASJC) codes

  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

Cite this

Self-propagating high-temperature synthesis of La(Sr)Ga(Mg)O3-δ for electrolyte of solid oxide fuel cells. / Ishikawa, Hiroyuki; Enoki, Makiko; Ishihara, Tatsumi; Akiyama, Tomohiro.

In: Journal of Alloys and Compounds, Vol. 430, No. 1-2, 14.03.2007, p. 246-251.

Research output: Contribution to journalArticle

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