Separation behavior of anions on ODS modified with phthalocyanine cobalt (III) complex

Eva Mecs Kocsis, Sadayuki Koizumi, Tadashi Sakane, Koji Takahashi, Toshihiko Imato

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

A stationary phase was prepared by modification of octadecyl silanized silica gels (ODS) with phthalocyanine cobalt (III) for separation of anions. The elution sequence of anions on the column packed with the modified ODS is in the order of Cl- < NO3 - < ClO4 - < I- < SCN- < NO2-, which was quite different from the elution sequence observed on a conventional anion exchange column. The strong retention of NO2 - on the column was explained by a result of adsorption experiment of NO2 - and NO3 - on the modified ODS.

Original languageEnglish
Pages (from-to)195-198
Number of pages4
JournalAnalytical Sciences
Volume13
Issue numberSUPPL.
Publication statusPublished - 1997

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Anions
Silica Gel
Adsorption
cobalt phthalocyanine
Experiments
perchlorate

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry

Cite this

Kocsis, E. M., Koizumi, S., Sakane, T., Takahashi, K., & Imato, T. (1997). Separation behavior of anions on ODS modified with phthalocyanine cobalt (III) complex. Analytical Sciences, 13(SUPPL.), 195-198.

Separation behavior of anions on ODS modified with phthalocyanine cobalt (III) complex. / Kocsis, Eva Mecs; Koizumi, Sadayuki; Sakane, Tadashi; Takahashi, Koji; Imato, Toshihiko.

In: Analytical Sciences, Vol. 13, No. SUPPL., 1997, p. 195-198.

Research output: Contribution to journalArticle

Kocsis, EM, Koizumi, S, Sakane, T, Takahashi, K & Imato, T 1997, 'Separation behavior of anions on ODS modified with phthalocyanine cobalt (III) complex', Analytical Sciences, vol. 13, no. SUPPL., pp. 195-198.
Kocsis EM, Koizumi S, Sakane T, Takahashi K, Imato T. Separation behavior of anions on ODS modified with phthalocyanine cobalt (III) complex. Analytical Sciences. 1997;13(SUPPL.):195-198.
Kocsis, Eva Mecs ; Koizumi, Sadayuki ; Sakane, Tadashi ; Takahashi, Koji ; Imato, Toshihiko. / Separation behavior of anions on ODS modified with phthalocyanine cobalt (III) complex. In: Analytical Sciences. 1997 ; Vol. 13, No. SUPPL. pp. 195-198.
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