Separation of Pallaium(II) an Rhoium(III) Using a Polymer Inclusion Membrane Containing a Phosphonium-Base Ionic Liqui Carrier

Aroit T.N. Fajar, Fukiko Kubota, Mochama L. Firmansyah, Masahiro Goto

Research output: Contribution to journalArticle

Abstract

In this stuy, we report the separation of P(II) an Rh(III) in a chlorie solution using a polymer inclusion membrane (PIM). We esigne a trioctyl(oecyl) phosphonium chlorie (P88812Cl) ionic liqui as a metal carrier for the PIM separation system. The effects of PIM composition an experimental conitions were systematically investigate. The concentrations of hyrochloric aci in the fee solution an thiourea in the receiving solution were foun to play a crucial role in the success of selective separation. Uner the optimize conitions, P(II) coul be effectively separate from Rh(III) with a 98% recovery yiel an 99% purity. We also compare the performance of our esigne carrier, P88812Cl, to that of commercially available ionic liqui trihexyl(tetraecyl) phosphonium chlorie (P66614Cl) using a 7-cycle reusability test. The P88812Cl showe a more stable performance an better urability compare with those of the commercial ionic liqui carrier.

Original languageEnglish
Pages (from-to)22334-22342
Number of pages9
JournalIndustrial and Engineering Chemistry Research
Volume58
Issue number49
DOIs
Publication statusPublished - Dec 11 2019

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Polymers
Membranes
Thiourea
Thioureas
Reusability
Metals
Recovery
Chemical analysis

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)
  • Industrial and Manufacturing Engineering

Cite this

Separation of Pallaium(II) an Rhoium(III) Using a Polymer Inclusion Membrane Containing a Phosphonium-Base Ionic Liqui Carrier. / Fajar, Aroit T.N.; Kubota, Fukiko; Firmansyah, Mochama L.; Goto, Masahiro.

In: Industrial and Engineering Chemistry Research, Vol. 58, No. 49, 11.12.2019, p. 22334-22342.

Research output: Contribution to journalArticle

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