Separation of Rare Earth Metals from Waste Television Tubes by Solvent Extraction Containing Calixarene Carboxyl Derivative

Kojiro Shimojo, Fukiko Kubota, Tatsuya Oshima, Masahiro Goto, Shintaro Furusaki

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

A solvent extraction technique was applied to the recovery of rare earth metals from waste television tubes. The acid leach solution of the fluorescent substance which is found in the TV tubes contains europium and yttrium as rare earth metals and a large amount of zinc ions. In the present study, calixarene carboxyl derivative was found to be very useful as an extractant for the separation of rare earth metals and zinc. The addition of sodium ions to the feed material solution strongly enhances the extraction ability in the calixarene extraction system. Further, the synergistic effect facilitates the separation efficiency between rare earth metals and zinc. solvent extraction, calixarene, lanthanoids, metal recycle, fluorescent substance.

Original languageEnglish
Pages (from-to)506-510
Number of pages5
Journalkagaku kogaku ronbunshu
Volume26
Issue number4
DOIs
Publication statusPublished - Jan 1 2000

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Rare Earth Metals
Calixarenes
Solvent extraction
Television
Rare earths
Derivatives
Zinc
Metals
Ions
Europium
Yttrium
Lanthanoid Series Elements
Sodium
Recovery
Acids

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Separation of Rare Earth Metals from Waste Television Tubes by Solvent Extraction Containing Calixarene Carboxyl Derivative. / Shimojo, Kojiro; Kubota, Fukiko; Oshima, Tatsuya; Goto, Masahiro; Furusaki, Shintaro.

In: kagaku kogaku ronbunshu, Vol. 26, No. 4, 01.01.2000, p. 506-510.

Research output: Contribution to journalArticle

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