Sequential carbometalation/elimination reaction takes place between gallium enolate and chloroethyne

Ryo Amemiya, Akiko Fujii, Mieko Arisawa, Masahiko Yamaguchi

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

In the presence of GaCl3, silyl enol ethers are sequentially ethynylated at the α-carbon atom with chlorotrimethylsilylethyne giving α-enynylated, α-endiynylated and α-entriynylated ketones.

Original languageEnglish
Pages (from-to)298-299
Number of pages2
JournalChemistry Letters
Volume32
Issue number3
DOIs
Publication statusPublished - Mar 5 2003
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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