Sequestering aromatic molecules with a spin-crossover Fe II microporous coordination polymer

Francisco J. Muñoz-Lara, Ana B. Gaspar, M. Carmen Muñoz, Masashi Arai, Susumu Kitagawa, Masaaki Ohba, José Antonio Real

Research output: Contribution to journalArticlepeer-review

63 Citations (Scopus)

Abstract

A novel Hoffman-like tri-dimensional coordination polymer {Fe(dpe)[Pt(CN) 4]}.0.5(dpe) based on the organic pillar ligand 1,2-di(4-pyridyl)ethylene (dpe; trans isomer), which exhibits spin crossover and porous properties was reported. Detection of the guest molecules was performed by analyzing the temperature dependence of the magnetic susceptibility of the corresponding clathrate. Single crystals of {Fe(dpe)[Pt(CN) 4]}.0.5(dpe) were grown by means of a slow diffusion technique. (NH 4) 2Fe(SO 4) 2.6H 2O dissolved in water was placed in one side of a multiarm-shaped vessel. The other arms contained a solution of dpe in methanol and a solution of K 2Pt(CN) 4.3H 2O in water. Square-shaped orange crystals of {Fe(dpe)[Pt(CN) 4]}.0.5(dpe) suitable for single crystal X-ray analysis were obtained after three weeks. Finger-print like magnetic response pattern to each analyte was attained.

Original languageEnglish
Pages (from-to)8013-8018
Number of pages6
JournalChemistry - A European Journal
Volume18
Issue number26
DOIs
Publication statusPublished - Jun 25 2012

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Organic Chemistry

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