Side-effect of ancillary ligand on electron transfer and photodynamics of a dinuclear valence tautomeric complex

Bao Li, Jun Tao, Hao Ling Sun, Osamu Sato, Rong Bin Huang, Lan Sun Zheng

Research output: Contribution to journalArticle

50 Citations (Scopus)

Abstract

A cobalt complex [{Co(dpqa)}2(dhbq)](PF6)3 (1(PF6)3, dhbq = deprotonated 2,5-dihydroxy-1,4- benzoquinone, dpqa = di(2-pyridylmethyl)-N-(quinolin-2-ylmethyl)amine) was prepared and studied by X-ray diffraction, electrochemistry, ESR, thermally and photo-induced magnetic measurements; the results show that the ancillary ligand finely tuned structural factors as well as intermolecular interactions that affect the VT behavior.

Original languageEnglish
Pages (from-to)2269-2271
Number of pages3
JournalChemical Communications
Issue number19
DOIs
Publication statusPublished - Jul 14 2008

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Magnetic variables measurement
Electrochemistry
Cobalt
Amines
Paramagnetic resonance
Ligands
X ray diffraction
Electrons
2,5-dihydroxy-1,4-benzoquinone

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Side-effect of ancillary ligand on electron transfer and photodynamics of a dinuclear valence tautomeric complex. / Li, Bao; Tao, Jun; Sun, Hao Ling; Sato, Osamu; Huang, Rong Bin; Zheng, Lan Sun.

In: Chemical Communications, No. 19, 14.07.2008, p. 2269-2271.

Research output: Contribution to journalArticle

Li, Bao ; Tao, Jun ; Sun, Hao Ling ; Sato, Osamu ; Huang, Rong Bin ; Zheng, Lan Sun. / Side-effect of ancillary ligand on electron transfer and photodynamics of a dinuclear valence tautomeric complex. In: Chemical Communications. 2008 ; No. 19. pp. 2269-2271.
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AU - Huang, Rong Bin

AU - Zheng, Lan Sun

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AB - A cobalt complex [{Co(dpqa)}2(dhbq)](PF6)3 (1(PF6)3, dhbq = deprotonated 2,5-dihydroxy-1,4- benzoquinone, dpqa = di(2-pyridylmethyl)-N-(quinolin-2-ylmethyl)amine) was prepared and studied by X-ray diffraction, electrochemistry, ESR, thermally and photo-induced magnetic measurements; the results show that the ancillary ligand finely tuned structural factors as well as intermolecular interactions that affect the VT behavior.

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