Side-effect of ancillary ligand on electron transfer and photodynamics of a dinuclear valence tautomeric complex

Bao Li, Jun Tao, Hao Ling Sun, Osamu Sato, Rong Bin Huang, Lan Sun Zheng

Research output: Contribution to journalArticle

53 Citations (Scopus)

Abstract

A cobalt complex [{Co(dpqa)}2(dhbq)](PF6)3 (1(PF6)3, dhbq = deprotonated 2,5-dihydroxy-1,4- benzoquinone, dpqa = di(2-pyridylmethyl)-N-(quinolin-2-ylmethyl)amine) was prepared and studied by X-ray diffraction, electrochemistry, ESR, thermally and photo-induced magnetic measurements; the results show that the ancillary ligand finely tuned structural factors as well as intermolecular interactions that affect the VT behavior.

Original languageEnglish
Pages (from-to)2269-2271
Number of pages3
JournalChemical Communications
Issue number19
DOIs
Publication statusPublished - 2008

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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