Silver ion oscillation through calix[4]azacrown tube

Jong Seung Kim; Seung Hwan Yang; Jeong Ah Rim; Jong Yeol Kim; Jacques Vicens; Seiji Shinkai

doi:10.1016/S0040-4039(01)01712-9

Silver ion oscillation through calix[4]azacrown tube

Jong Seung Kim, Seung Hwan Yang, Jeong Ah Rim, Jong Yeol Kim, Jacques Vicens, Seiji Shinkai

Institute for Advanced Study

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

Silver ion oscillation through calixtube of 1,3-alternate calix[4]crown-5-azacrown-5 and 1,3-alternate calix[4]-bis-azacrown-5 was investigated by temperature variable ¹H NMR experiment. The latter (symmetrical calix-bis-azacrown-5) showed an intramolecular metal ion tunneling through π-basic calixtube while the former did not.

Original language	English
Pages (from-to)	8047-8050
Number of pages	4
Journal	Tetrahedron Letters
Volume	42
Issue number	45
DOIs	https://doi.org/10.1016/S0040-4039(01)01712-9
Publication status	Published - Nov 5 2001

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(01)01712-9

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@article{8eeb2935a94246bbb97ea4c825947803,

title = "Silver ion oscillation through calix[4]azacrown tube",

abstract = "Silver ion oscillation through calixtube of 1,3-alternate calix[4]crown-5-azacrown-5 and 1,3-alternate calix[4]-bis-azacrown-5 was investigated by temperature variable 1H NMR experiment. The latter (symmetrical calix-bis-azacrown-5) showed an intramolecular metal ion tunneling through π-basic calixtube while the former did not.",

author = "Kim, {Jong Seung} and Yang, {Seung Hwan} and Rim, {Jeong Ah} and Kim, {Jong Yeol} and Jacques Vicens and Seiji Shinkai",

note = "Funding Information: This work was supported by Grant 2000-1-12300-001-3 from the Basic Research Program of the Korea Science and Engineering Foundation. We thank the Korea Basic Science Institute in Taejon, Korea, for use of the Bruker ARX-600 NMR spectrometer.",

year = "2001",

month = nov,

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doi = "10.1016/S0040-4039(01)01712-9",

language = "English",

volume = "42",

pages = "8047--8050",

journal = "Tetrahedron Letters",

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TY - JOUR

T1 - Silver ion oscillation through calix[4]azacrown tube

AU - Kim, Jong Seung

AU - Yang, Seung Hwan

AU - Rim, Jeong Ah

AU - Kim, Jong Yeol

AU - Vicens, Jacques

AU - Shinkai, Seiji

N1 - Funding Information: This work was supported by Grant 2000-1-12300-001-3 from the Basic Research Program of the Korea Science and Engineering Foundation. We thank the Korea Basic Science Institute in Taejon, Korea, for use of the Bruker ARX-600 NMR spectrometer.

PY - 2001/11/5

Y1 - 2001/11/5

N2 - Silver ion oscillation through calixtube of 1,3-alternate calix[4]crown-5-azacrown-5 and 1,3-alternate calix[4]-bis-azacrown-5 was investigated by temperature variable 1H NMR experiment. The latter (symmetrical calix-bis-azacrown-5) showed an intramolecular metal ion tunneling through π-basic calixtube while the former did not.

AB - Silver ion oscillation through calixtube of 1,3-alternate calix[4]crown-5-azacrown-5 and 1,3-alternate calix[4]-bis-azacrown-5 was investigated by temperature variable 1H NMR experiment. The latter (symmetrical calix-bis-azacrown-5) showed an intramolecular metal ion tunneling through π-basic calixtube while the former did not.

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U2 - 10.1016/S0040-4039(01)01712-9

DO - 10.1016/S0040-4039(01)01712-9

M3 - Article

AN - SCOPUS:0035813402

SN - 0040-4039

VL - 42

SP - 8047

EP - 8050

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 45

ER -

Silver ion oscillation through calix[4]azacrown tube

Abstract

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