Single-molecule dynamics in a self-assembled 2D molecular sieve

Guillaume Schull, Ludovic Douillard, Céline Fiorini-Debuisschert, Fabrice Charra, Fabrice Mathevet, David Kreher, André Jean Attias

    Research output: Contribution to journalArticlepeer-review

    143 Citations (Scopus)

    Abstract

    A two-dimensional molecular sieve has been realized. It consists of a host matrix of molecularly engineered building blocks self-assembled at the liquid-solid interface. The simultaneous size- and shape-dependent dynamics of different guest molecules is observed in situ, in real time with submolecular resolution using a scanning tunneling microscope both at the liquid-solid interface and under vacuum. The temperature-dependent dynamics reveals that the diffusion proceeds through thermally activated channeling between single-molecule surface cavities.

    Original languageEnglish
    Pages (from-to)1360-1363
    Number of pages4
    JournalNano Letters
    Volume6
    Issue number7
    DOIs
    Publication statusPublished - Jul 1 2006

    All Science Journal Classification (ASJC) codes

    • Bioengineering
    • Chemistry(all)
    • Materials Science(all)
    • Condensed Matter Physics
    • Mechanical Engineering

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