Singly N-confused [26]hexaphyrin

A binucleating porphyrinoid ligand for mixed metals in different oxidation states

Sabapathi Gokulnath, Keisuke Yamaguchi, Motoki Toganoh, Shigeki Mori, Hidemitsu Uno, Hiroyuki Furuta

Research output: Contribution to journalArticle

29 Citations (Scopus)

Abstract

(Chemical Equation Presented) Mix and match: The title porphyrinoid has been synthesized and shows unique coordination chemistry by incorporating two different metals with different oxidation states (see figure). X-ray crystallography was used to confirm that a rectangular conformation in both mono- and binuclear complexes was retained.

Original languageEnglish
Pages (from-to)2302-2306
Number of pages5
JournalAngewandte Chemie - International Edition
Volume50
Issue number10
DOIs
Publication statusPublished - Mar 1 2011

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X ray crystallography
Conformations
Metals
Ligands
Oxidation

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Catalysis

Cite this

Singly N-confused [26]hexaphyrin : A binucleating porphyrinoid ligand for mixed metals in different oxidation states. / Gokulnath, Sabapathi; Yamaguchi, Keisuke; Toganoh, Motoki; Mori, Shigeki; Uno, Hidemitsu; Furuta, Hiroyuki.

In: Angewandte Chemie - International Edition, Vol. 50, No. 10, 01.03.2011, p. 2302-2306.

Research output: Contribution to journalArticle

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