Size-selective and reversible encapsulation of single small hydrocarbon molecules by a cavitand-porphyrin species

Jun Nakazawa, Jun Hagiwara, Maki Mizuki, Yuichi Shimazaki, Fumito Tani, Yoshinori Naruta

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

(Figure Presented) An accommodating host: A new capsule-shaped host molecule, the cavitand-porphyrin shown, reversibly encapsulates single hydrocarbon molecules smaller than propane (see picture). With the exception of acetylene, the binding affinities are inversely correlated with the size of the guest hydrocarbons.

Original languageEnglish
Pages (from-to)3744-3746
Number of pages3
JournalAngewandte Chemie - International Edition
Volume44
Issue number24
DOIs
Publication statusPublished - Jun 13 2005

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Porphyrins
Hydrocarbons
Encapsulation
Acetylene
Propane
Molecules
Capsules
cavitand

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Size-selective and reversible encapsulation of single small hydrocarbon molecules by a cavitand-porphyrin species. / Nakazawa, Jun; Hagiwara, Jun; Mizuki, Maki; Shimazaki, Yuichi; Tani, Fumito; Naruta, Yoshinori.

In: Angewandte Chemie - International Edition, Vol. 44, No. 24, 13.06.2005, p. 3744-3746.

Research output: Contribution to journalArticle

Nakazawa, Jun ; Hagiwara, Jun ; Mizuki, Maki ; Shimazaki, Yuichi ; Tani, Fumito ; Naruta, Yoshinori. / Size-selective and reversible encapsulation of single small hydrocarbon molecules by a cavitand-porphyrin species. In: Angewandte Chemie - International Edition. 2005 ; Vol. 44, No. 24. pp. 3744-3746.
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