Sizeable red-shift of absorption and fluorescence of subporphyrazine induced by peripheral push and pull substitution

Xu Liang, Soji Shimizu, Nagao Kobayashi

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Peripheral substitution with electron-donating (push) and electron-withdrawing (pull) substituents caused a sizeable red-shift of the Q band absorption and fluorescence of subporphyrazine, and the red-shift was controlled by the push substituents. Control of the chromophore symmetry and inherent molecular chirality arising from the pattern of substitution were also investigated.

Original languageEnglish
Pages (from-to)13781-13784
Number of pages4
JournalChemical Communications
Volume50
Issue number89
DOIs
Publication statusPublished - Nov 18 2014

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Substitution reactions
Fluorescence
Electrons
Chirality
Chromophores
Absorption spectra

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Sizeable red-shift of absorption and fluorescence of subporphyrazine induced by peripheral push and pull substitution. / Liang, Xu; Shimizu, Soji; Kobayashi, Nagao.

In: Chemical Communications, Vol. 50, No. 89, 18.11.2014, p. 13781-13784.

Research output: Contribution to journalArticle

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