Slow magnetic relaxation in a 4,2-ribbon like FeIII 2CoII heterobimetallic chain

Soonchul Kang, Shinji Kanegawa, Osamu Sato

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Abstract

The reaction of Co(NO3)2·6H2O and 3-benzoylpyridine with the low-spin iron(iii) complex, H[FeIII(phen) (CN)4], in methanol gives rise to a cyanide-bridged heterobimetallic chain [{FeIII(phen)(CN)4}2Co II(3-bpe)2] (1) that exhibits intrachain ferromagnetic coupling and slow double magnetic relaxation.

Original languageEnglish
Pages (from-to)13575-13577
Number of pages3
JournalDalton Transactions
Volume41
Issue number44
DOIs
Publication statusPublished - Nov 28 2012

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All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

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