Small-angle scattering study of mesoscopic structures in charged gel and their evolution on dehydration

Masaaki Sugiyama, Masahiko Annaka, Kazuhiro Hara, Martin E. Vigild, George D. Wignall

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

Mesoscopic structures, with length scales ∼102 Å, were investigated by small-angle X-ray and neutron scattering (SAXS and SANS) in several N-isopropylacrylamide-sodium acrylate (NIPA-SA) copolymeric hydrogels with varying [NIPA]/[SA] ratios and water contents. The SAXS experiments reveal that, depending upon the [NIPA]/[SA] ratio, the dehydrated NIPA-SA gel shows two mesoscopic structures: one consists of randomly distributed SA-rich islands in NIPA matrix, while the other is a microphase-separated structure, composed of NIPA-rich and SA-rich domains. In addition, the SANS experiments reveal the mesoscopic structural features during the dehydration process. As the concentration of the network polymers increases, NIPA-rich and water-rich domains segregate in the gel. Then, an electrostatic interaction between the segregated domains induces a microphase-separated structure in the limit of the dehydrated NIPA-SA gel.

Original languageEnglish
Pages (from-to)6300-6308
Number of pages9
JournalJournal of Physical Chemistry B
Volume107
Issue number26
Publication statusPublished - Jul 3 2003

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films
  • Materials Chemistry

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