Sm(Sr)CoO3 cone cathode on LaGaO3 thin film electrolyte for IT-SOFC with high power density

Young Wan Ju, Toru Inagaki, Shintaro Ida, Tatsumi Ishihara

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

Cone-shaped Sm0.5Sr0.5CoO3- (SSC) layer was fabricated by a pulsed laser deposition (PLD) method on the Sm 0.2Ce0.8O2- (SDC)/La0.9Sr 0.1Ga0.8Mg0.2O3- (LSGM) bi-layer electrolyte film for metallic anode supported intermediate temperature solid oxide fuel cells. Effect of SSC layer on the power generation property and optimum fabrication condition of SSC layer has been investigated. By inserting SSC layer, power generation property and thermal cycling durability was improved due to increased contact strength and expanded oxygen ion conduction pathway. Especially, the cell having 500 nm thickness SSC layer showed higher power density than that of the cell without SSC layer. The maximum power density (MPD) of the cell was 1.99, 1.10 and 0.53 W/cm2 at 973, 873 and 773 K, respectively. In addition, after third thermal cycling from 973 to 298 K (decreasing and increasing rate; 200 K/h), the decrease in MPD was only 6. The cell also showed a stable power generating performance under a constant current condition.

Original languageEnglish
JournalJournal of the Electrochemical Society
Volume158
Issue number7
DOIs
Publication statusPublished - Jun 1 2011

Fingerprint

Thermal cycling
Solid oxide fuel cells (SOFC)
Electrolytes
Power generation
Cones
radiant flux density
cones
Cathodes
cathodes
electrolytes
Thin films
Pulsed laser deposition
thin films
Anodes
Durability
Ions
Oxygen
Fabrication
cells
cycles

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films
  • Electrochemistry
  • Materials Chemistry

Cite this

Sm(Sr)CoO3 cone cathode on LaGaO3 thin film electrolyte for IT-SOFC with high power density. / Ju, Young Wan; Inagaki, Toru; Ida, Shintaro; Ishihara, Tatsumi.

In: Journal of the Electrochemical Society, Vol. 158, No. 7, 01.06.2011.

Research output: Contribution to journalArticle

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