SnIV complexes of N-confused porphyrins and oxoporphyrins - Unique fluorescence "switch-on" halide receptors

Yongshu Xie, Tatsuki Morimoto, Hiroyuki Furuta

    Research output: Contribution to journalArticlepeer-review

    75 Citations (Scopus)

    Abstract

    Confused, but not dazed: Totally in contrast to SnIV complexes of normal porphyrins, SnIV complexes of N-confused oxoporphyrins can strongly bind halides at the axial position with pronounced fluorescence enhancement (see scheme; Ar = Ph, p-CF3C6H4, p-CH3C6H4) and can thus be regarded as a novel prototype of fluorescence halide sensors. (Chemical Equation Presented)

    Original languageEnglish
    Pages (from-to)6907-6910
    Number of pages4
    JournalAngewandte Chemie - International Edition
    Volume45
    Issue number41
    DOIs
    Publication statusPublished - Oct 20 2006

    All Science Journal Classification (ASJC) codes

    • Catalysis
    • Chemistry(all)

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