Abstract
Redox-stable solid oxide fuel cell (SOFC) anodes are developed in order to improve durability at higher fuel utilization, as a possible alternative to conventional Ni-zirconia cermet anodes. Ce 0.9 Gd 0.1 O 2 (GDC) is utilized as a mixed ionic and electronic conductor (MIEC), in combination with Sr 0.9 La 0.1 TiO 3 (LST) as an electronic conductor. The stability of noble metals (Rh, Pt, and Pd) is analyzed via thermochemical calculation of stable phases. Noble metal catalyst nanoparticles are incorporated via co-impregnation with GDC. The electrochemical characteristics of SOFC single cells using these anode materials are investigated in highly-humidified H 2 at 800 °C. Their stability at high fuel utilization is analyzed. These co-impregnated anodes with highly dispersed noble metal catalysts on the LST-GDC conducting backbones, achieve high I[sbnd]V performance comparable to conventional Ni-cermet anodes. The co-impregnated anodes also achieve considerably high catalytic mass activity. At higher oxygen partial pressure, where the Ni catalyst can be deactivated by oxidation, these noble catalysts are thermochemically stable in the metallic state, and tolerant against oxidation. This class of alternative catalyst, impregnated with low-loading of noble metals could contribute to stable operation in the downstream region of SOFC systems. A simple cost analysis indicates a tolerance of using noble metals, provided their loading is sufficiently low.
| Original language | English |
|---|---|
| Pages (from-to) | 8502-8518 |
| Number of pages | 17 |
| Journal | International Journal of Hydrogen Energy |
| Volume | 44 |
| Issue number | 16 |
| DOIs | |
| Publication status | Published - Mar 29 2019 |
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All Science Journal Classification (ASJC) codes
- Renewable Energy, Sustainability and the Environment
- Fuel Technology
- Condensed Matter Physics
- Energy Engineering and Power Technology
Cite this
SOFC anodes impregnated with noble metal catalyst nanoparticles for high fuel utilization. / Futamura, Shotaro; Muramoto, Aki; Tachikawa, Yuya; Matsuda, Junko; Lyth, Stephen M.; Shiratori, Yusuke; Taniguchi, Shunsuke; Sasaki, Kazunari.
In: International Journal of Hydrogen Energy, Vol. 44, No. 16, 29.03.2019, p. 8502-8518.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - SOFC anodes impregnated with noble metal catalyst nanoparticles for high fuel utilization
AU - Futamura, Shotaro
AU - Muramoto, Aki
AU - Tachikawa, Yuya
AU - Matsuda, Junko
AU - Lyth, Stephen M.
AU - Shiratori, Yusuke
AU - Taniguchi, Shunsuke
AU - Sasaki, Kazunari
PY - 2019/3/29
Y1 - 2019/3/29
N2 - Redox-stable solid oxide fuel cell (SOFC) anodes are developed in order to improve durability at higher fuel utilization, as a possible alternative to conventional Ni-zirconia cermet anodes. Ce 0.9 Gd 0.1 O 2 (GDC) is utilized as a mixed ionic and electronic conductor (MIEC), in combination with Sr 0.9 La 0.1 TiO 3 (LST) as an electronic conductor. The stability of noble metals (Rh, Pt, and Pd) is analyzed via thermochemical calculation of stable phases. Noble metal catalyst nanoparticles are incorporated via co-impregnation with GDC. The electrochemical characteristics of SOFC single cells using these anode materials are investigated in highly-humidified H 2 at 800 °C. Their stability at high fuel utilization is analyzed. These co-impregnated anodes with highly dispersed noble metal catalysts on the LST-GDC conducting backbones, achieve high I[sbnd]V performance comparable to conventional Ni-cermet anodes. The co-impregnated anodes also achieve considerably high catalytic mass activity. At higher oxygen partial pressure, where the Ni catalyst can be deactivated by oxidation, these noble catalysts are thermochemically stable in the metallic state, and tolerant against oxidation. This class of alternative catalyst, impregnated with low-loading of noble metals could contribute to stable operation in the downstream region of SOFC systems. A simple cost analysis indicates a tolerance of using noble metals, provided their loading is sufficiently low.
AB - Redox-stable solid oxide fuel cell (SOFC) anodes are developed in order to improve durability at higher fuel utilization, as a possible alternative to conventional Ni-zirconia cermet anodes. Ce 0.9 Gd 0.1 O 2 (GDC) is utilized as a mixed ionic and electronic conductor (MIEC), in combination with Sr 0.9 La 0.1 TiO 3 (LST) as an electronic conductor. The stability of noble metals (Rh, Pt, and Pd) is analyzed via thermochemical calculation of stable phases. Noble metal catalyst nanoparticles are incorporated via co-impregnation with GDC. The electrochemical characteristics of SOFC single cells using these anode materials are investigated in highly-humidified H 2 at 800 °C. Their stability at high fuel utilization is analyzed. These co-impregnated anodes with highly dispersed noble metal catalysts on the LST-GDC conducting backbones, achieve high I[sbnd]V performance comparable to conventional Ni-cermet anodes. The co-impregnated anodes also achieve considerably high catalytic mass activity. At higher oxygen partial pressure, where the Ni catalyst can be deactivated by oxidation, these noble catalysts are thermochemically stable in the metallic state, and tolerant against oxidation. This class of alternative catalyst, impregnated with low-loading of noble metals could contribute to stable operation in the downstream region of SOFC systems. A simple cost analysis indicates a tolerance of using noble metals, provided their loading is sufficiently low.
UR - http://www.scopus.com/inward/record.url?scp=85062359025&partnerID=8YFLogxK
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U2 - 10.1016/j.ijhydene.2019.01.223
DO - 10.1016/j.ijhydene.2019.01.223
M3 - Article
AN - SCOPUS:85062359025
VL - 44
SP - 8502
EP - 8518
JO - International Journal of Hydrogen Energy
JF - International Journal of Hydrogen Energy
SN - 0360-3199
IS - 16
ER -