Abstract
We have demonstrated that a one-dimensional molecular assembly created by an H-aggregated porphyrin·Cu(II) stack can be immobilized, without a morphological change, by sol-gel polycondensation of the peripheral triethoxysilyl groups. The resultant gel prepared according to this flowchart has gained a very high thermal stability as well as a unique mechanical strength.
Original language | English |
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Pages (from-to) | 7298-7299 |
Number of pages | 2 |
Journal | Journal of the American Chemical Society |
Volume | 127 |
Issue number | 20 |
DOIs | |
Publication status | Published - May 25 2005 |
All Science Journal Classification (ASJC) codes
- Catalysis
- Chemistry(all)
- Biochemistry
- Colloid and Surface Chemistry