Solidification of Graphene-Assisted Phase Change Nanocomposites inside a Sphere for Cold Storage Applications

Rajendran Prabakaran, Shaji Sidney, Dhasan Mohan Lal, C. Selvam, Sivasankaran Harish

Research output: Contribution to journalArticle

Abstract

In this work, we experimentally investigated the solidification behavior of functionalized graphene-based phase change nanocomposites inside a sphere. The influence of graphene nanoplatelets on thermal transport and rheological characteristics of the such nanocomposites were also discussed. We adopted the covalent functionalization method to prepare highly stable phase change nanocomposites using commercially available phase change material (PCM) OM08 as the host matrix and graphene nanoplatelets (GnPs) with 0.1, 0.3, and 0.5 volume percentage as the nano inclusions. We report a maximum thermal conductivity enhancement of ~102 and ~46% with 0.5 vol% in the solid and liquid states, respectively. Rheological measurements show that the pure PCM shows Newtonian behavior, whereas the inclusion of GnPs leads to the transition to non-Newtonian behavior, especially at lower shear rates. Viscosity of the nanocomposite increases with an increase in the volume fraction of GnP. For 0.5 vol% of GnPs, maximum increase in viscosity was found to be ~37% at a shear rate of 1000 s−1. Time required for complete solidification decreases with the loading of GnPs. Maximum reduction in solidification time with 0.5 vol% of GnPs was ~40% for bath temperature of −10C.

Original languageEnglish
Article number3473
JournalEnergies
Volume12
Issue number18
DOIs
Publication statusPublished - Sep 9 2019

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Cold storage
Graphene
Nanocomposites
Phase Change
Solidification
Phase Change Material
Phase change materials
Shear deformation
Viscosity
Inclusion
Functionalization
Thermal Conductivity
Volume Fraction
Percentage
Volume fraction
Thermal conductivity
Enhancement
Liquid
Decrease
Liquids

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Energy Engineering and Power Technology
  • Energy (miscellaneous)
  • Control and Optimization
  • Electrical and Electronic Engineering

Cite this

Solidification of Graphene-Assisted Phase Change Nanocomposites inside a Sphere for Cold Storage Applications. / Prabakaran, Rajendran; Sidney, Shaji; Lal, Dhasan Mohan; Selvam, C.; Harish, Sivasankaran.

In: Energies, Vol. 12, No. 18, 3473, 09.09.2019.

Research output: Contribution to journalArticle

Prabakaran, Rajendran ; Sidney, Shaji ; Lal, Dhasan Mohan ; Selvam, C. ; Harish, Sivasankaran. / Solidification of Graphene-Assisted Phase Change Nanocomposites inside a Sphere for Cold Storage Applications. In: Energies. 2019 ; Vol. 12, No. 18.
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