Solubilities and diffusion coefficients of high boiling compounds in supercritical carbon dioxide

Hidenori Higashi, Yoshio Iwai, Yasuhiko Arai

Research output: Contribution to journalReview article

51 Citations (Scopus)

Abstract

A brief introduction of the data sources and the applications of correlation methods for the solubilities and diffusion coefficients of hig-boiling compounds (mainly in solid state) in supercritical carbon dioxide are reviewed. Empirical equations, equations of state, solution models, and the Monte Carlo simulation for the calculation of solubilities in supercritical carbon dioxide are discussed. The application of empirical equation based on the Stokes-Einstein model, rough hard sphere theory, Schmidt number correlation, and molecular dynamics simulation for the calculation of diffusion coefficients in supercritical carbon dioxide at infinite dilution condition are reviewed. Further, the application of the Darken equation and the Leffler and Cullinan equation for the calculation of concentration dependence of diffusion coefficients in supercritical carbon dioxide is presented.

Original languageEnglish
Pages (from-to)3027-3044
Number of pages18
JournalChemical Engineering Science
Volume56
Issue number10
DOIs
Publication statusPublished - Jun 12 2001

Fingerprint

Solubility
Carbon Dioxide
Boiling liquids
Diffusion Coefficient
Carbon dioxide
Number theory
Correlation methods
Hard Spheres
Stokes
Equations of state
Equation of State
Molecular Dynamics Simulation
Dilution
Albert Einstein
Rough
Molecular dynamics
Monte Carlo Simulation
Computer simulation
Model

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)
  • Industrial and Manufacturing Engineering

Cite this

Solubilities and diffusion coefficients of high boiling compounds in supercritical carbon dioxide. / Higashi, Hidenori; Iwai, Yoshio; Arai, Yasuhiko.

In: Chemical Engineering Science, Vol. 56, No. 10, 12.06.2001, p. 3027-3044.

Research output: Contribution to journalReview article

@article{94a49dc432584c0ca93038777ae2c6db,
title = "Solubilities and diffusion coefficients of high boiling compounds in supercritical carbon dioxide",
abstract = "A brief introduction of the data sources and the applications of correlation methods for the solubilities and diffusion coefficients of hig-boiling compounds (mainly in solid state) in supercritical carbon dioxide are reviewed. Empirical equations, equations of state, solution models, and the Monte Carlo simulation for the calculation of solubilities in supercritical carbon dioxide are discussed. The application of empirical equation based on the Stokes-Einstein model, rough hard sphere theory, Schmidt number correlation, and molecular dynamics simulation for the calculation of diffusion coefficients in supercritical carbon dioxide at infinite dilution condition are reviewed. Further, the application of the Darken equation and the Leffler and Cullinan equation for the calculation of concentration dependence of diffusion coefficients in supercritical carbon dioxide is presented.",
author = "Hidenori Higashi and Yoshio Iwai and Yasuhiko Arai",
year = "2001",
month = "6",
day = "12",
doi = "10.1016/S0009-2509(01)00003-3",
language = "English",
volume = "56",
pages = "3027--3044",
journal = "Chemical Engineering Science",
issn = "0009-2509",
publisher = "Elsevier BV",
number = "10",

}

TY - JOUR

T1 - Solubilities and diffusion coefficients of high boiling compounds in supercritical carbon dioxide

AU - Higashi, Hidenori

AU - Iwai, Yoshio

AU - Arai, Yasuhiko

PY - 2001/6/12

Y1 - 2001/6/12

N2 - A brief introduction of the data sources and the applications of correlation methods for the solubilities and diffusion coefficients of hig-boiling compounds (mainly in solid state) in supercritical carbon dioxide are reviewed. Empirical equations, equations of state, solution models, and the Monte Carlo simulation for the calculation of solubilities in supercritical carbon dioxide are discussed. The application of empirical equation based on the Stokes-Einstein model, rough hard sphere theory, Schmidt number correlation, and molecular dynamics simulation for the calculation of diffusion coefficients in supercritical carbon dioxide at infinite dilution condition are reviewed. Further, the application of the Darken equation and the Leffler and Cullinan equation for the calculation of concentration dependence of diffusion coefficients in supercritical carbon dioxide is presented.

AB - A brief introduction of the data sources and the applications of correlation methods for the solubilities and diffusion coefficients of hig-boiling compounds (mainly in solid state) in supercritical carbon dioxide are reviewed. Empirical equations, equations of state, solution models, and the Monte Carlo simulation for the calculation of solubilities in supercritical carbon dioxide are discussed. The application of empirical equation based on the Stokes-Einstein model, rough hard sphere theory, Schmidt number correlation, and molecular dynamics simulation for the calculation of diffusion coefficients in supercritical carbon dioxide at infinite dilution condition are reviewed. Further, the application of the Darken equation and the Leffler and Cullinan equation for the calculation of concentration dependence of diffusion coefficients in supercritical carbon dioxide is presented.

UR - http://www.scopus.com/inward/record.url?scp=0035329655&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0035329655&partnerID=8YFLogxK

U2 - 10.1016/S0009-2509(01)00003-3

DO - 10.1016/S0009-2509(01)00003-3

M3 - Review article

AN - SCOPUS:0035329655

VL - 56

SP - 3027

EP - 3044

JO - Chemical Engineering Science

JF - Chemical Engineering Science

SN - 0009-2509

IS - 10

ER -