Solubilities of Hydrocarbon Gases in Polybutadiene

Shigeru Ituno, Mitsuru Ohzono, Yoshio Iwai, Yasuhiko Arai

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

In the polymer industry, separation equipment is required to separate unreacted monomers and solvents from polymers. In order to design such equipment, solubilities of gases and vapors in polymers are needed as fundamental data. Therefore, solubilities of twenty-one hydrocarbon gases and vapors for polybutadiene were measured by use of a gas chromatographic technique in the temperature range from 150 to 225°C under atmospheric pressure. on the basis of the thermodynamic relation between solubility and temperature, the heats of solution for these hydrocarbons were obtained. It is very helpful if the solubility can be estimated by a predictive method. The UNIFAC-FV model has been applied to calculate the solubilities of these hydrocarbon gases and vapors in polybutadiene. The solubilities calculated are in good agreement with experimental results.

Original languageEnglish
Pages (from-to)73-76
Number of pages4
JournalKOBUNSHI RONBUNSHU
Volume42
Issue number1
DOIs
Publication statusPublished - Jan 1 1985

Fingerprint

Polybutadienes
Hydrocarbons
solubility
Solubility
Gases
hydrocarbon
gas
Polymers
polymer
Vapors
atmospheric pressure
Atmospheric pressure
polybutadiene
Monomers
thermodynamics
temperature
Thermodynamics
Temperature
industry
Industry

All Science Journal Classification (ASJC) codes

  • Chemical Engineering (miscellaneous)
  • Materials Science (miscellaneous)
  • Environmental Science(all)
  • Polymers and Plastics

Cite this

Solubilities of Hydrocarbon Gases in Polybutadiene. / Ituno, Shigeru; Ohzono, Mitsuru; Iwai, Yoshio; Arai, Yasuhiko.

In: KOBUNSHI RONBUNSHU, Vol. 42, No. 1, 01.01.1985, p. 73-76.

Research output: Contribution to journalArticle

Ituno, Shigeru ; Ohzono, Mitsuru ; Iwai, Yoshio ; Arai, Yasuhiko. / Solubilities of Hydrocarbon Gases in Polybutadiene. In: KOBUNSHI RONBUNSHU. 1985 ; Vol. 42, No. 1. pp. 73-76.
@article{ba569e88946a4c4084844a57e7077f9b,
title = "Solubilities of Hydrocarbon Gases in Polybutadiene",
abstract = "In the polymer industry, separation equipment is required to separate unreacted monomers and solvents from polymers. In order to design such equipment, solubilities of gases and vapors in polymers are needed as fundamental data. Therefore, solubilities of twenty-one hydrocarbon gases and vapors for polybutadiene were measured by use of a gas chromatographic technique in the temperature range from 150 to 225°C under atmospheric pressure. on the basis of the thermodynamic relation between solubility and temperature, the heats of solution for these hydrocarbons were obtained. It is very helpful if the solubility can be estimated by a predictive method. The UNIFAC-FV model has been applied to calculate the solubilities of these hydrocarbon gases and vapors in polybutadiene. The solubilities calculated are in good agreement with experimental results.",
author = "Shigeru Ituno and Mitsuru Ohzono and Yoshio Iwai and Yasuhiko Arai",
year = "1985",
month = "1",
day = "1",
doi = "10.1295/koron.42.73",
language = "English",
volume = "42",
pages = "73--76",
journal = "Kobunshi Ronbunshu",
issn = "0386-2186",
publisher = "The Society of Polymer Science, Japan",
number = "1",

}

TY - JOUR

T1 - Solubilities of Hydrocarbon Gases in Polybutadiene

AU - Ituno, Shigeru

AU - Ohzono, Mitsuru

AU - Iwai, Yoshio

AU - Arai, Yasuhiko

PY - 1985/1/1

Y1 - 1985/1/1

N2 - In the polymer industry, separation equipment is required to separate unreacted monomers and solvents from polymers. In order to design such equipment, solubilities of gases and vapors in polymers are needed as fundamental data. Therefore, solubilities of twenty-one hydrocarbon gases and vapors for polybutadiene were measured by use of a gas chromatographic technique in the temperature range from 150 to 225°C under atmospheric pressure. on the basis of the thermodynamic relation between solubility and temperature, the heats of solution for these hydrocarbons were obtained. It is very helpful if the solubility can be estimated by a predictive method. The UNIFAC-FV model has been applied to calculate the solubilities of these hydrocarbon gases and vapors in polybutadiene. The solubilities calculated are in good agreement with experimental results.

AB - In the polymer industry, separation equipment is required to separate unreacted monomers and solvents from polymers. In order to design such equipment, solubilities of gases and vapors in polymers are needed as fundamental data. Therefore, solubilities of twenty-one hydrocarbon gases and vapors for polybutadiene were measured by use of a gas chromatographic technique in the temperature range from 150 to 225°C under atmospheric pressure. on the basis of the thermodynamic relation between solubility and temperature, the heats of solution for these hydrocarbons were obtained. It is very helpful if the solubility can be estimated by a predictive method. The UNIFAC-FV model has been applied to calculate the solubilities of these hydrocarbon gases and vapors in polybutadiene. The solubilities calculated are in good agreement with experimental results.

UR - http://www.scopus.com/inward/record.url?scp=0022281183&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0022281183&partnerID=8YFLogxK

U2 - 10.1295/koron.42.73

DO - 10.1295/koron.42.73

M3 - Article

AN - SCOPUS:0022281183

VL - 42

SP - 73

EP - 76

JO - Kobunshi Ronbunshu

JF - Kobunshi Ronbunshu

SN - 0386-2186

IS - 1

ER -