Solvent-dependent investigation of carbazole benzonitrile derivatives

Does the le 3 - CT 1 energy gap facilitate thermally activated delayed fluorescence?

Takuya Hosokai, Hiroki Noda, Hajime Nakanotani, Takanori Nawata, Yasuo Nakayama, Hiroyuki Matsuzaki, Chihaya Adachi

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The photophysical properties of six types of carbazole benzonitrile (CzBN) derivatives are investigated in different solvents to examine the thermally activated delayed fluorescence (TADF) activation via reducing the energy gap between the singlet charge-transfer and triplet locally excited states, ΔEST(LE). Relative to the ΔEST(LE) values for the CzBN derivatives in the low polarity solvent toluene (ϵ∼2), a reduction of ΔEST(LE) for the CzBN derivatives in the polar solvent acetonitrile (ϵ∼37) was confirmed while maintaining fairly constant ΔEST values. Notably, TADF activation was observed in acetonitrile for some CzBN derivatives that are TADF inactive in toluene. A numerical analysis of various rate constants revealed the cause of TADF activation as an increase in the reverse intersystem crossing rate and a suppression of the non-radiative decay rate of the triplet states. The positive effect of ΔEST(LE) was limited, however, as an excessive decrease in ΔEST(LE) facilitates the nonradiative deactivation of the triplet states, leading to a loss of the TADF efficiency. This paper shows that ΔEST(LE) provides a measure of TADF activation and that appropriate regulation of ΔEST(LE) is required to achieve high TADF efficiency.

Original languageEnglish
Article number032102
JournalJournal of Photonics for Energy
Volume8
Issue number3
DOIs
Publication statusPublished - Jul 1 2018

Fingerprint

carbazoles
Energy gap
Fluorescence
Derivatives
fluorescence
Chemical activation
activation
Acetonitrile
atomic energy levels
acetonitrile
Toluene
toluene
Excited states
deactivation
decay rates
numerical analysis
Charge transfer
Numerical analysis
Rate constants
polarity

All Science Journal Classification (ASJC) codes

  • Atomic and Molecular Physics, and Optics
  • Renewable Energy, Sustainability and the Environment

Cite this

Solvent-dependent investigation of carbazole benzonitrile derivatives : Does the le 3 - CT 1 energy gap facilitate thermally activated delayed fluorescence? / Hosokai, Takuya; Noda, Hiroki; Nakanotani, Hajime; Nawata, Takanori; Nakayama, Yasuo; Matsuzaki, Hiroyuki; Adachi, Chihaya.

In: Journal of Photonics for Energy, Vol. 8, No. 3, 032102, 01.07.2018.

Research output: Contribution to journalArticle

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