Solvent Extraction Equilibria of Rare Earth Metals by Acidic Organophosphorus Extractants with Bulky Substituents

Keisuke Ohto, Sachiyo Yoshida, Kazuharu Yoshizuka, Katsutoshi Inoue, Masaru Ohtsuka, Masahiro Goto, Fumiyuki Nakashio

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Two kinds of acidic organophosphonates with different bulky ester groups, 2-[p-(1,1,3,3-tetramethylbutyl)phenoxy]ethyl and p-(1,1,3,3-tetramethylbutyl)phenyl groups, were synthesized to investigate their extraction behavior for nine kinds of rare earth elements from aqueous acidic nitrate media. The extraction reaction was discussed based on the slope analysis to evaluate the extraction equilibrium constants (Kex) for each metal ion and the separation factors (β). These extractants synthesized in the present work were found to possess stronger extractabilities for rare earth metals than commercial extractants like D2EHPA and PC-88A. Their separation efficiencies are also comparable with the commercial extractants mentioned above.

Original languageEnglish
Pages (from-to)637-641
Number of pages5
Journalanalytical sciences
Volume11
Issue number4
DOIs
Publication statusPublished - Jan 1 1995

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Rare Earth Metals
Solvent extraction
Organophosphonates
Equilibrium constants
Rare earth elements
Nitrates
Metal ions
Esters

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry

Cite this

Solvent Extraction Equilibria of Rare Earth Metals by Acidic Organophosphorus Extractants with Bulky Substituents. / Ohto, Keisuke; Yoshida, Sachiyo; Yoshizuka, Kazuharu; Inoue, Katsutoshi; Ohtsuka, Masaru; Goto, Masahiro; Nakashio, Fumiyuki.

In: analytical sciences, Vol. 11, No. 4, 01.01.1995, p. 637-641.

Research output: Contribution to journalArticle

Ohto, Keisuke ; Yoshida, Sachiyo ; Yoshizuka, Kazuharu ; Inoue, Katsutoshi ; Ohtsuka, Masaru ; Goto, Masahiro ; Nakashio, Fumiyuki. / Solvent Extraction Equilibria of Rare Earth Metals by Acidic Organophosphorus Extractants with Bulky Substituents. In: analytical sciences. 1995 ; Vol. 11, No. 4. pp. 637-641.
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