Speciation Studies of Some Metal Complexes with L-Aspartyl-L-phenylalanine Methyl Ester by Potentiometry

Makoto AiHARA, Fudeko Tanaka, Minori Fujimoto, Ko Takehara

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The stoichiometry and stability constants of the complexes formed between nickel(II), cobalt(II), copper(II) and manganese(II) with L-aspartyl-L-phenylalanine methyl ester (aspartame, LH) have been determined potentiometrically at 25° C and m=0.1. Nickel(II) and cobalt(II) react with aspartame to form ML, ML2 and ML3 type complexes. Copper(II) forms ML and ML2 type complexes. On the other hand, manganese(II) forms ML type complexes. The Irving-Williams’ order, Co(II)<Ni(II)<Cu(II), was found to be satisfied for ML+ complexes. Complex distribution depending on pH and metal/ aspartame ratio is given for these systems.

Original languageEnglish
Pages (from-to)755-759
Number of pages5
Journalanalytical sciences
Volume8
Issue number6
DOIs
Publication statusPublished - Jan 1 1992

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Aspartame
Coordination Complexes
Phenylalanine
Manganese
Cobalt
Nickel
Copper
Stoichiometry
Metals
phenylalanine methyl ester

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry

Cite this

Speciation Studies of Some Metal Complexes with L-Aspartyl-L-phenylalanine Methyl Ester by Potentiometry. / AiHARA, Makoto; Tanaka, Fudeko; Fujimoto, Minori; Takehara, Ko.

In: analytical sciences, Vol. 8, No. 6, 01.01.1992, p. 755-759.

Research output: Contribution to journalArticle

AiHARA, Makoto ; Tanaka, Fudeko ; Fujimoto, Minori ; Takehara, Ko. / Speciation Studies of Some Metal Complexes with L-Aspartyl-L-phenylalanine Methyl Ester by Potentiometry. In: analytical sciences. 1992 ; Vol. 8, No. 6. pp. 755-759.
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