Specific Intermolecular Interactions by the Localized π-Electrons in C70-fullerene

Takuya Kubo, Eisuke Kanao, Takatoshi Matsumoto, Toyohiro Naito, Tomoharu Sano, Mingdi Yan, Koji Otsuka

Research output: Contribution to journalArticlepeer-review

7 Citations (Scopus)

Abstract

We report the specific intermolecular interactions on C70-fullerene. A newly developed silica-monolithic capillary column, which was modified with C70-fullerene via a particular thermal reactive molecule, perfluorophenyl azide, provided a selective retention behavior toward polycyclic aromatic hydrocarbons in liquid chromatography. Especially, a hemispherical molecule, i. e., corannulene, was significantly retained on this C70-fullerene column. Results of the computer simulation of the molecules suggested that the specific interaction might be caused by the deflection of the π-electrons-density in C70-fullerene. Furthermore, the absorption spectrometry also indicated that the absorption spectra of C70-fullerene with/without corannulene were dramatically changed by the specific interaction, whereas no spectrum differences were observed with C60-fullerene.

Original languageEnglish
Pages (from-to)5900-5904
Number of pages5
JournalChemistrySelect
Volume1
Issue number18
DOIs
Publication statusPublished - Nov 1 2016
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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