Spectroscopy and excited-state dynamics of benzene-trimer ion

Kazuhiko Ohashi, Y. Nakai, T. Shibata, N. Nishi

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The photodissociation of (C6H6)3 + is studied in the range hν = 0.9-3.0 eV. The electronic spectrum of (C6H6)3 + shows the main band at hν ≈ 1.29 eV and a side band at ≈ 1.02 eV. The (C6H6)3 + ion retains spectroscopic features characteristic of (C6H6)2 +, suggesting that the positive charge is carried by a dimer subunit in (C6H6)3 +. The major fragment ion changes smoothly from (C6H6)2 + to C6H6 + with increasing photon energy from 0.9 to 1.8 eV. The product branching ratios and the kinetic energy of the C6H6 + fragment are consistent with a two-step model for the formation of C6H6 +.

Original languageEnglish
Pages (from-to)601-605
Number of pages5
JournalSurface Review and Letters
Volume3
Issue number1
DOIs
Publication statusPublished - Jan 1 1996

    Fingerprint

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films
  • Materials Chemistry

Cite this