Spherulite formation from microphase-separated lamellae in semi-crystalline diblock copolymer comprising polyethylene and atactic polypropylene blocks

Masaya Ueda, Kazuo Sakurai, Shigeru Okamoto, David J. Lohse, William J. MacKnight, Seiji Shinkai, Shinichi Sakurai, Shunji Nomura

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

The characteristics of crystallization in a semi-crystalline block copolymer have been experimentally examined using small-angle X-ray scattering and small-angle light scattering. For this purpose, a flow-oriented polyethylene-block-(atactic polypropylene) diblock copolymer with Mw = 113 kg/mol and apolyethylene volume fraction of 0.48 was used. First of all, the crystallization was found to be much suppressed as compared to that of polyethylene homopolymer (homo-PE), as evidenced by a crystallinity that was approximately one-third of homo-PE. Spherulite growth with rupturing the microphase-separated lamellae (micro-LAM) was found at crystallization temperatures in the range 95 ≤ Tc ≤ 101°C. That is, spherulites can grow even if the crystallization is initiated in the spatially confining micro-LAM structure. However, it was further found that the micro-LAM structure did not co-exist with a spherulite. On the other hand, at much lower crystallization temperatures (Tc < 95°C), the micro-LAM structure was retained whereas no spherulites formed. The suppression of spherulite formation can be accounted for by an auto-decelerating effect of nuclei in a confining microdomain space.

Original languageEnglish
Pages (from-to)6995-7005
Number of pages11
Journalpolymer
Volume44
Issue number22
DOIs
Publication statusPublished - Oct 3 2003

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Polypropylenes
Polyethylene
Crystallization
Block copolymers
Polyethylenes
Crystalline materials
Homopolymerization
X ray scattering
Light scattering
Volume fraction
Temperature

All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Polymers and Plastics
  • Materials Chemistry

Cite this

Spherulite formation from microphase-separated lamellae in semi-crystalline diblock copolymer comprising polyethylene and atactic polypropylene blocks. / Ueda, Masaya; Sakurai, Kazuo; Okamoto, Shigeru; Lohse, David J.; MacKnight, William J.; Shinkai, Seiji; Sakurai, Shinichi; Nomura, Shunji.

In: polymer, Vol. 44, No. 22, 03.10.2003, p. 6995-7005.

Research output: Contribution to journalArticle

Ueda, M, Sakurai, K, Okamoto, S, Lohse, DJ, MacKnight, WJ, Shinkai, S, Sakurai, S & Nomura, S 2003, 'Spherulite formation from microphase-separated lamellae in semi-crystalline diblock copolymer comprising polyethylene and atactic polypropylene blocks', polymer, vol. 44, no. 22, pp. 6995-7005. https://doi.org/10.1016/S0032-3861(03)00697-9
Ueda, Masaya ; Sakurai, Kazuo ; Okamoto, Shigeru ; Lohse, David J. ; MacKnight, William J. ; Shinkai, Seiji ; Sakurai, Shinichi ; Nomura, Shunji. / Spherulite formation from microphase-separated lamellae in semi-crystalline diblock copolymer comprising polyethylene and atactic polypropylene blocks. In: polymer. 2003 ; Vol. 44, No. 22. pp. 6995-7005.
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