Spin-crossover behaviors in solvated cobalt(ii) compounds

Shinya Hayami, Manabu Nakaya, Hitomi Ohmagari, Amolegbe Saliu Alao, Masaaki Nakamura, Ryo Ohtani, Ryotaro Yamaguchi, Takayoshi Kuroda-Sowa, Jack K. Clegg

Research output: Contribution to journalArticlepeer-review

26 Citations (Scopus)

Abstract

Two solvated cobalt(ii) terpyridine complexes, [Co(MeO-terpy)2](BF4)2·H2O (1·H2O) and [Co(MeO-terpy)2](BF4)2·acetone (1·acetone) were prepared. Annealing each of these complexes resulted in the formation of two desolvated species, 1 and 1′, respectively. 1·H2O and 1 exhibited two-step and gradual SCO. The compound 1·acetone has high-spin at all temperatures and 1′ undergoes a reverse spin transition due to a phase change.

Original languageEnglish
Pages (from-to)9345-9348
Number of pages4
JournalDalton Transactions
Volume44
Issue number20
DOIs
Publication statusPublished - May 28 2015
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

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