Spin crossover characteristics of nanofibrous FeII-1,2,4- triazole complexes in liquid crystals

Research output: Contribution to journalArticle

35 Citations (Scopus)

Abstract

A lipophilic linear FeII complex is dispersed as nanofibers in nematic liquid crystals and displays spin-crossover at temperatures higher than those observed for the bulk crystalline state; thermal bistability is also induced in the liquid crystal environment, reflecting increased ligand field splitting energy and enhanced cooperativity by liquid crystals.

Original languageEnglish
Pages (from-to)1229-1231
Number of pages3
JournalChemical Communications
Volume46
Issue number8
DOIs
Publication statusPublished - Feb 16 2010

Fingerprint

Liquid Crystals
Liquid crystals
Nematic liquid crystals
Nanofibers
Display devices
Ligands
Crystalline materials
Temperature
1,2,4-triazole
Hot Temperature

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Spin crossover characteristics of nanofibrous FeII-1,2,4- triazole complexes in liquid crystals. / Kuroiwa, Keita; Kikuchi, Hirotsugu; Kimizuka, Nobuo.

In: Chemical Communications, Vol. 46, No. 8, 16.02.2010, p. 1229-1231.

Research output: Contribution to journalArticle

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