Spreading and structuring of water on superhydrophilic polyelectrolyte brush surfaces

Daiki Murakami, Motoyasu Kobayashi, Taro Moriwaki, Yuka Ikemoto, Hiroshi Jinnai, Atsushi Takahara

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

The wetting behavior of superhydrophilic polyelectrolyte brushes was investigated. Reflection interference contrast microscopy demonstrated that the contact angles of water on the polyelectrolyte brushes were extremely low but remained finite in the range of <3. The presence of water molecules was evident, even outside the macroscopic water droplet. These water molecules were confined to the thin brush layers and contained a highly ordered hydrogen bond network, which was identified as structural water. The presence of the thin film and the structural water changed the surface energies, which prevented the complete wetting of the surface.

Original languageEnglish
Pages (from-to)1148-1151
Number of pages4
JournalLangmuir
Volume29
Issue number4
DOIs
Publication statusPublished - Jan 29 2013

Fingerprint

brushes
Brushes
Polyelectrolytes
Water
water
wetting
Wetting
Molecules
Interfacial energy
surface energy
Contact angle
molecules
Hydrogen bonds
Microscopic examination
hydrogen bonds
microscopy
interference
Thin films
thin films

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Spectroscopy
  • Electrochemistry

Cite this

Spreading and structuring of water on superhydrophilic polyelectrolyte brush surfaces. / Murakami, Daiki; Kobayashi, Motoyasu; Moriwaki, Taro; Ikemoto, Yuka; Jinnai, Hiroshi; Takahara, Atsushi.

In: Langmuir, Vol. 29, No. 4, 29.01.2013, p. 1148-1151.

Research output: Contribution to journalArticle

Murakami, Daiki ; Kobayashi, Motoyasu ; Moriwaki, Taro ; Ikemoto, Yuka ; Jinnai, Hiroshi ; Takahara, Atsushi. / Spreading and structuring of water on superhydrophilic polyelectrolyte brush surfaces. In: Langmuir. 2013 ; Vol. 29, No. 4. pp. 1148-1151.
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