Stabilization of crown-based organogelators by charge-transfer interaction

Jong Hwa Jung; Soo Jin Lee; Jeong Ah Rim; Haeseong Lee; Tae Sung Bae; Shim Sung Lee; Seiji Shinkai

doi:10.1021/cm048643r

Stabilization of crown-based organogelators by charge-transfer interaction

Jong Hwa Jung, Soo Jin Lee, Jeong Ah Rim, Haeseong Lee, Tae Sung Bae, Shim Sung Lee, Seiji Shinkai

Institute for Advanced Study

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

Crown-based organogelators 1 and 2 bearing long alkyl chains were synthesized. Their gelation abilities were drastically enhanced by addition of bypyridinium-based ion (3²⁺), suggesting the bridging effect of the bipyridinium-based ion could be the primary driving force for the stabilization of organogel systems due to the intermolecular charge-transfer interaction with the 1:2 stoichiometry.

Original language	English
Pages (from-to)	459-462
Number of pages	4
Journal	Chemistry of Materials
Volume	17
Issue number	3
DOIs	https://doi.org/10.1021/cm048643r
Publication status	Published - Feb 8 2005

All Science Journal Classification (ASJC) codes

Chemistry(all)
Chemical Engineering(all)
Materials Chemistry

Access to Document

10.1021/cm048643r

Cite this

@article{e33b5fc1422e4e578c9baec85a5f6df2,

title = "Stabilization of crown-based organogelators by charge-transfer interaction",

abstract = "Crown-based organogelators 1 and 2 bearing long alkyl chains were synthesized. Their gelation abilities were drastically enhanced by addition of bypyridinium-based ion (32+), suggesting the bridging effect of the bipyridinium-based ion could be the primary driving force for the stabilization of organogel systems due to the intermolecular charge-transfer interaction with the 1:2 stoichiometry.",

author = "Jung, {Jong Hwa} and Lee, {Soo Jin} and Rim, {Jeong Ah} and Haeseong Lee and Bae, {Tae Sung} and Lee, {Shim Sung} and Seiji Shinkai",

year = "2005",

month = feb,

day = "8",

doi = "10.1021/cm048643r",

language = "English",

volume = "17",

pages = "459--462",

journal = "Chemistry of Materials",

issn = "0897-4756",

publisher = "American Chemical Society",

number = "3",

}

TY - JOUR

T1 - Stabilization of crown-based organogelators by charge-transfer interaction

AU - Jung, Jong Hwa

AU - Lee, Soo Jin

AU - Rim, Jeong Ah

AU - Lee, Haeseong

AU - Bae, Tae Sung

AU - Lee, Shim Sung

AU - Shinkai, Seiji

PY - 2005/2/8

Y1 - 2005/2/8

N2 - Crown-based organogelators 1 and 2 bearing long alkyl chains were synthesized. Their gelation abilities were drastically enhanced by addition of bypyridinium-based ion (32+), suggesting the bridging effect of the bipyridinium-based ion could be the primary driving force for the stabilization of organogel systems due to the intermolecular charge-transfer interaction with the 1:2 stoichiometry.

AB - Crown-based organogelators 1 and 2 bearing long alkyl chains were synthesized. Their gelation abilities were drastically enhanced by addition of bypyridinium-based ion (32+), suggesting the bridging effect of the bipyridinium-based ion could be the primary driving force for the stabilization of organogel systems due to the intermolecular charge-transfer interaction with the 1:2 stoichiometry.

UR - http://www.scopus.com/inward/record.url?scp=13444304310&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=13444304310&partnerID=8YFLogxK

U2 - 10.1021/cm048643r

DO - 10.1021/cm048643r

M3 - Article

AN - SCOPUS:13444304310

VL - 17

SP - 459

EP - 462

JO - Chemistry of Materials

JF - Chemistry of Materials

SN - 0897-4756

IS - 3

ER -

Stabilization of crown-based organogelators by charge-transfer interaction

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this