Stepwise π-extension of meso-alkylidenyl porphyrins through sequential 1,3-dipolar cycloaddition and redox reactions

Dowoo Park, Seung Doo Jeong, Masatoshi Ishida, Chang Hee Lee

Research output: Contribution to journalArticlepeer-review

9 Citations (Scopus)

Abstract

Several regioselectively π-extended, pyrrole fused porphyrinoids have been synthesized by the 1,3-dipolar cycloaddition of meso-alkylidene-(benzi)porphyrins. Pd(ii) complexes gave oxidation resistant, bis-pyrrole fused adducts. The repeated 1,3-dipolar cycloaddition followed by oxidation–reduction of pentaphyrin analogs afforded π-extended porphyrin analogs.

Original languageEnglish
Pages (from-to)9277-9280
Number of pages4
JournalChemical Communications
Volume50
Issue number66
DOIs
Publication statusPublished - Jul 22 2014

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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