Stepwise adsorption of metal alkoxides on hydrolyzed surfaces: A surface sol-gel process

Izumi Ichinose, Hiroyuki Senzu, Toyoki Kunitake

Research output: Contribution to journalArticle

141 Citations (Scopus)

Abstract

Ultrathin films of TiO2-based gel were prepared by repeating adsorption of titanium(IV) butoxide (Ti(O-nBu)4) and subsequent hydrolysis of the surface. Linear film growth was observed for at least 20 cycles, as monitored by quartz crystal microbalance (QCM). Similar thin films were prepared from aluminum(III) butoxide (Al(O-nBu)3), zirconium (IV) propoxide (Zr(O-nPr)4), niobium(V) butoxide (Nb(O-nBu)5), tetramethyl orthosilicate (Si(O-Me)4), and their combinations.

Original languageEnglish
Pages (from-to)831-832
Number of pages2
JournalChemistry Letters
Issue number10
DOIs
Publication statusPublished - Jan 1 1996

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Niobium
Ultrathin films
Quartz crystal microbalances
Film growth
Titanium
Aluminum
Sol-gel process
Hydrolysis
Gels
Metals
Adsorption
Thin films
tetramethyl orthosilicate

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Stepwise adsorption of metal alkoxides on hydrolyzed surfaces : A surface sol-gel process. / Ichinose, Izumi; Senzu, Hiroyuki; Kunitake, Toyoki.

In: Chemistry Letters, No. 10, 01.01.1996, p. 831-832.

Research output: Contribution to journalArticle

Ichinose, Izumi ; Senzu, Hiroyuki ; Kunitake, Toyoki. / Stepwise adsorption of metal alkoxides on hydrolyzed surfaces : A surface sol-gel process. In: Chemistry Letters. 1996 ; No. 10. pp. 831-832.
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