Stepwise radial complexation from the outer layer to the inner layer of a dendritic ligand: a phenylazomethine dendrimer with an inverted coordination sequence

Ken Albrecht, Noriko Sakane, Kimihisa Yamamoto

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

A para-substituted phenylazomethine dendrimer (pGnA) coordinates to Lewis acids in a stepwise radial fashion from the inner layer to the outer layer. The inversion of this coordination sequence was achieved for the first time by just changing the substitution position of the phenylazomethine group from the para position to the meta position (mGnA).

Original languageEnglish
Pages (from-to)12177-12180
Number of pages4
JournalChemical Communications
Volume50
Issue number81
DOIs
Publication statusPublished - Sep 16 2014
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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