Stepwise synthesis and magnetic control of trimetallic magnets [Co 2Ln(L)2(H2O)4][Cr(CN)6] ·nH2O (Ln = La, Gd; H2L = 2,6-di(acetoacetyl) pyridine) with 3-D pillared-layer structure

Takuya Shiga, Hisashi Ökawa, Susumu Kitagawa, Masaaki Ohba

Research output: Contribution to journalArticlepeer-review

135 Citations (Scopus)

Abstract

Integration of mononuclear [Cr(CN)6]3- and preorganized trinuclear [Co2Ln(L)2]3+ complexes provides novel trimetallic magnets having a 3-D pillared-layer framework with an alternate array of 2-D layer extended by Cr(III)?CN?Co(II) linkages and Ln(III) ion. The overall magnetic nature can be systematically controlled by Ln(III) ions inserted between the 2-D ferromagnetic layers.

Original languageEnglish
Pages (from-to)16426-16427
Number of pages2
JournalJournal of the American Chemical Society
Volume128
Issue number51
DOIs
Publication statusPublished - Dec 27 2006
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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