Integration of mononuclear [Cr(CN)6]3- and preorganized trinuclear [Co2Ln(L)2]3+ complexes provides novel trimetallic magnets having a 3-D pillared-layer framework with an alternate array of 2-D layer extended by Cr(III)?CN?Co(II) linkages and Ln(III) ion. The overall magnetic nature can be systematically controlled by Ln(III) ions inserted between the 2-D ferromagnetic layers.
|Number of pages||2|
|Journal||Journal of the American Chemical Society|
|Publication status||Published - Dec 27 2006|
All Science Journal Classification (ASJC) codes
- Colloid and Surface Chemistry